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Electrowinning is defined as the cathodic deposition of metal, in this example copper, from a copper bearing solution by the passage of an electric current current using an insoluble anode. For copper the electrowinning reaction reaction is: CuSO4 + H2O ⇒ Cu + ½O2 + H2SO4 The overall reaction is the combination of two electrochemical half reactions.

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The electrowinning of copper ions derived from leaching, or solvent extraction, is a significant contributor to the global copper commodity supply. The process of electrolysis for copper was first developed in the late 19th century and despite numerous advancements in technology, the principles and basic equipment remain the same.

The electrowinning method for treating high copper cyanide solution was investigated by thermodynamics analysis and experiment. The influences of copper concentration, solution temperature, electrolysis time, current density and flow rate on copper recovery and current efficiency was studied in detail and the suitable operation parameters were chosen.

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